I thought Ninjask evolved into Shedinja. I was adamant on completing my dex in Ruby, so I trained my Jask to level 65... then when that failed I tried trading it with various items. You can only imagine my frustration when I found out it evolved
(or rather appeared out of nowhere)in a special way :s
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Black 2 FC: 3053 3827 7149
Besides the common misconception of Luvdisc evolving into Alomomola (before it's revealed to not be the case), which would be awesome, I used to think that Slowbro (not Slowpoke) evolves into Slowking, because they just look like they could form an entire evolutionary line. Do you know how I learned that it's not the case? I was impatient with evolving Slowpoke into Slowbro to evolve Slowking, so I just traded Slowpoke with that King's Rock, and viola! The evolution happened! I found that amazing.
Thanks for reading.
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Bonus articles: Mega Evolution Candidates (Part 7) -- Generation 6 Pokémon (07/12/2013)