I ship Ash with a lot of people, and I multiship Ashley as well.
xPaul, xGary, xMay, xPikachu, xBrock, xDrew, xBarry, xIris, xDento, xMorison ect.
Paul gets shipped quite a bit as well.
xAsh, xBarry, xSilver, xReggie, xMaylene, xCynthia, xChimchar
Gold would also count
xSilver, xChrys, xRed, xGreen, xEmerald, xBlue, xYellow